Pressure swing adsorption technology
The technology of air-to-nitrogen production with the use of adsorption processes in nitrogen generators is well studied and widely applied at industrial facilities for the recovery of high-purity nitrogen.
The operating principle of a nitrogen generator utilizing the adsorption technology is based upon the dependence of the adsorption rates featured by various gas mixture components upon pressure and temperature factors. Among nitrogen adsorption plants of various types, PSA nitrogen gas generator have found the broadest application world-wide.
The system's design is based on the regulation of gas adsorption and adsorbent regeneration by means of changing pressures in two adsorber–adsorbent-containing vessels. This process requires constant temperature, close to ambient. With this process, nitrogen is produced by the plant at the above-atmospheric pressure, while the adsorbent regeneration is accomplished at below-atmospheric pressure.
The swing adsorption process in each of the two adsorbers consists of two stages running for a few minutes. At the adsorption stage oxygen, H2O and CO2 molecules diffuse into the pore structure of the adsorbent whilst the nitrogen molecules are allowed to travel through the adsorber–adsorbent-containing vessel. At the regeneration stage the adsorbed components are released from the adsorbent vented into the atmosphere. The process is then multiplely repeated.
The advantages of PSA
High nitrogen purity:
PSA nitrogen gas generator plants allow production of high-purity nitrogen from air, which membrane systems are unable to provide – up to 99.9995% nitrogen. But in most cases they do not produce more than 98.8% nitrogen with the remainder being argon that is not separated from the nitrogen by the usual PSA process. The argon is not normally a problem, as argon is more inert than nitrogen. This nitrogen purity may also be ensured by cryogenic systems, but they are considerably more complex and justified only by large consumption volumes. The nitrogen generators use CMS (carbon molecular sieve) technology to produce a continuous supply of ultra high purity nitrogen and are available with internal compressors or without.
Low operating costs:
By substitution of out-of-date air separation plants nitrogen production savings largely exceed 50%. The net cost of nitrogen produced by nitrogen generators is significantly less than the cost of bottled or liquefied nitrogen.
Environmental impact:
Generating nitrogen gas by PSA is a sustainable, environmentally friendly and energy efficient approach to providing pure, clean, dry nitrogen gas. Compared to the energy needed for a cryogenic air separation plant and the energy needed to transport the liquid nitrogen from the plant to the facility, generated nitrogen consumes less energy and creates far fewer greenhouse gases.
Applications of nitrogen generators
Food and beverage industries:
The moment food or beverages are produced, or fruits and vegetables harvested, an aging process kicks in until the complete decay of the products. This is caused by chemical reactions with oxygen, bacteria and other organisms. Generators are used to flood the products with N2 that displaces the oxygen and prolongs the product lifetime significantly because these organisms cannot develop. Furthermore, chemical degradation of food caused by oxidation can be eliminated or stopped.
Analytical chemistry:
PSA nitrogen gas generator is required for various forms of analytical chemistry such as liquid chromatography–mass spectrometry and gas chromatography where a stable and continuous supply of nitrogen is necessary.
Chemical and petrochemical industries:
The primary and very important application of nitrogen in chemical and petrochemical industries is the provision of inert environment aimed at ensuring general industrial safety during cleaning and protection of process vessels. In addition, nitrogen is used for pipelines pressure testing, chemical agents transportation, and regeneration of used catalysts in technological processes.
Fire Protection:
The fire protection industry uses nitrogen gas for two different applications - fire suppression and corrosion prevention. Nitrogen generators are used in hypoxic air fire prevention systems to produce air with a low oxygen content which will suppress a fire. To prevent corrosion, nitrogen generators are used in place of or in conjunction with a compressed air system to provide supervisory nitrogen gas in place of air for dry pipe and pre-action fire sprinkler systems.
Petroleum industry:
In the petroleum industry, nitrogen is an indispensable component in a number of processes. Most commonly, nitrogen is used to create an inert environment for preventing explosions and for fire safety and to support transportation and transfer of hydrocarbons. Additionally, nitrogen is used for pipeline testing and purging, cleaning technological vessels and cleaning liquefied gas carriers and hydrocarbon storage facilities.
FAQ
Q: How do I determine the size of my nitrogen generator?
Q: How does a nitrogen generator work?
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